Faraday’s Laws of Electrolysis
Faraday’s Laws of Electrolysis: Overview
This topic covers concepts, such as, Faraday's Laws of Electrolysis, Faraday's First Law of Electrolysis, Faraday's Law for Gaseous Electrolytic Product & Current Efficiency etc.
Important Questions on Faraday’s Laws of Electrolysis
Consider the reaction :
The electricity in coulombs required to reduce 1 mol of would be:

A current of is passed through of solution of for with a current efficiency . Find out the molarity of after the deposition of . Assume the volume of the solution to remain constant during the electrolysis.

Calculate the quantity of electricity that would be required to reduce 12.3 g of nitrobenzene to aniline, if the current efficiency for the process is 50 per cent. If the potential drop across the cell is 3.0 volts, how much energy will be consumed?

In a fuel cell, hydrogen and oxygen react to produce electricity. In the process, hydrogen gas is oxidised at the anode and oxygen is reduced at the cathode. If of at react in minutes, what is the average current produced? If the entire current is used for electro deposition of copper from copper solution, how many grams of copper will be deposited?
Anode reaction:
Cathode reaction:

Chromium metal can be plated out from an acidic solution containing according to the following equation.
Determine the following :
(i) The amount of chromium that will be plated out by coulombs.
(ii) The time it will take to plate out of chromium by using current.

Chromium metal can be plated out from an acidic solution containing according to the following equation:
Calculate:
(i) The amount of chromium that will be plated out by .
(ii) The time it will take to plate out of chromium by using current.

An aqueous solution of on electrolysis gives according to the reaction:
A direct current of with a current efficiency of is passed through of solution ( by weight). The reaction taking place at the anode and the cathode are:
Reaction at anode:
Reaction at cathode:
The time it will take to produce of and the molarity of the solution with respect to hydroxide ion would be (if it is assumed that there is no loss because of evaporation):

The charge in coulombs of 1 gram of ion

The electric charge for electrode deposition of one gram equivalent of a substance is:

Faraday’s laws of electrolysis are related to the:

Electrolysis of dilute aqueous solution was carried out by passing milli ampere current. The time required to liberate of gas at the cathode is :

Aluminium oxide may be electrolysed at to give Al metal (at mass = 27 amu, 1F = 96,500 C). To prepare 5.12 kg of Al would require

The weight of silver deposited when faraday current is passed through silver nitrate solution.

An electric current is passed through silver nitrate solution using silver electrodes. of silver was found to be deposited on cathode. What will be the weight of copper deposited on cathode if same amount of electricity is passed through copper sulphate solution using copper electrodes?

amalgam is prepared by electrolysis of aqueous using cathode How much current is to be passed through solution for seconds to prepare a amalgam with by weight

Same quantity of electricity was passed through solutions of salts of elements and with atomic masses and respectively. The masses of and deposited were and respectively. The valence's of and respectively are

Salts of and were electrolyzed under identical conditions using the same quantity of electricity. It was found that when of was deposited. The weights of and deposited were and respectively. If the atomic mass of and respectively are and then the valancies of and respectively are ______

Oxidation of succinate ion produces ethylene and carbon dioxide gases. What is the total volume of gases (at both cathode and anode) at STP ( and ) On passing Faraday electricity through an aqueous solution of potassium succinate,?

How long (approximate) should water be electrolysed by passing through current so that the oxygen released can completely burn of diborane? (Atomic weight of )

What is the correct graph from the following? If during electrolysis the amount of product liberated at electrode is plotted against charge in Faraday.
